Radical <i>trans</i>-Hydroboration of Substituted 1,3-Diynes with an <i>N</i>‑Heterocyclic Carbene Borane
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资源简介：
Monohydroboration of substituted 1,3-diynes with an N-heterocyclic carbene borane (NHC–borane) occurs under radical conditions using an azo initiator, such as ACCN and AIBN, and a thiol as a polarity-reversal catalyst. The reaction is highly regio- and stereoselective and provides stable NHC-(E)-alkynylalkenylboranes.
创建时间：
2021-01-22
