Designed Molecular Switches: Controlling the Conformation of Benzamido-diphenylacetylenes
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With the goal of creating a molecular switch, the hydrogen-bonded diphenylacetylene structure has been modified such that an equilibrium now exists between two intramolecular H-bonded states. Through X-ray crystallography and 1H NMR analysis it is shown that this equilibrium can be biased in a predictable manner by modulating the relative acidity of the amide NH’s.
创建时间：
2010-08-20
