Isolable Dibenzo[<i>a,e</i>]disilapentalene with a Dichotomic Reactivity toward CO₂

The first dibenzo­[a,e]­disilapentalene with two SiC moieties in the heteropentalene core has been prepared. Its solid-state structure and density functional theory (DFT) calculations revealed that the SiC bonds are involved in an expanded π-conjugated system. The SiC bonds show a distinguished reactivity toward CO2, depending on the reaction conditions. While one product results from fixation of two CO2 molecules across one SiC bond, two different products could be isolated from the reaction of three CO2 molecules with both SiC bonds. The mechanism has been uncovered by DFT calculations.