Asymmetric Conjugate Addition of Silyl Enol Ethers Catalyzed by Tethered Bis(8-quinolinolato) Aluminum Complexes
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
New chiral tethered bis(8-quinolinolato) (TBOx) aluminum(III) complexes effectively catalyze the highly enantioselective Mukaiyama−Michael reaction of silyl enol ethers, including tetrasubstituted enolates that give rise to enantioenriched α-carbonyl all-carbon-substituted quaternary stereocenters. The present catalyst also promotes the conjugate addition of N-benzylindole to α,β-unsaturated acylphosphonates with high enantioselectivity (indole Friedel−Crafts alkylation reaction).
创建时间：
2007-01-31
