Synthesis of Pincer Iridium Complexes Bearing a Boron Atom and <sup><i>i</i></sup>Pr-Substituted Phosphorus Atoms: Application to Catalytic Transfer Dehydrogenation of Alkanes
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An iPr-substituted PBP-pincer ligand was synthesized and introduced to iridium metal to give iPr-(PBP)Ir(H)Cl and iPr-(PBP)Ir(C2H4) complexes. Both of these complexes were found to be moderately active for the catalytic transfer dehydrogenation of cyclooctane.
创建时间:
2016-02-13



