Ruthenium Cluster Mediated Transformation of Linear Alkenes into Trienyl Ligands. Activation of Five C(sp3)−H Bonds of 1-Octene, 1-Nonene, and 1-Decene
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The treatment of [Ru6(μ3-H)2(μ5-κ2-ampy)(CO)16] (H2ampy = 2-amino-6-methylpyridine) with 1-octene, 1-nonene, and 1-decene affords heptanuclear derivatives containing trienyl ligands that arise from the unusual activation of five C(sp3)−H bonds of linear alkenes.
创建时间：
2007-05-07
