Organocatalytic Enantioselective Selenosulfonylation of a C–C Double Bond To Form Two Stereogenic Centers in an Aqueous Medium
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Organocatalytic selenosulfonylation of the C–C double bond of α,β-unsaturated ketones to construct two contiguous stereogenic centers in an aqueous medium was described. A series of α-selenyl and β-sulfonyl ketones with various functional groups were synthesized in good yields and enantioselectivities with saturated NaCl solution as the solvent. In addition, this protocol had been successfully scaled up to a decagram scale via a simple workup procedure.
创建时间：
2019-05-22
