Catalytic Enantioselective Additions of Indoles to Nitroalkenes

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https://figshare.com/articles/dataset/Catalytic_Enantioselective_Additions_of_Indoles_to_Nitroalkenes/2893540 数据链接链接失效反馈

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Catalytic Enantioselective Additions of Indoles to Nitroalkenes

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2008-12-10

Stereodefined Access to Lactams via Olefin Difunctionalization: Iridium Nitrenoids as a Motif of LUMO-Controlled Dipoles

催化不对称合成

氮转移反应

Reported herein is a general platform of a stereodefined access to γ-lactams via Cp*Ir-catalyzed olefin difunctionalization, where in situ generated Ir-nitrenoid is utilized as a key motif of 1,3-dipo

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Sequential Visible-Light Photoactivation and Palladium Catalysis Enabling Enantioselective [4+2] Cycloadditions

催化不对称合成

光诱导有机反应

Catalytic asymmetric cycloadditions of reactive ketene intermediates provide new opportunities for the production of chiral heterocyclic molecules. Though known for over 100 years, ketenes still remai

NIAID Data Ecosystem40

Enantioselective Ni-Catalyzed Electrochemical Synthesis of Biaryl Atropisomers

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电化学合成

A scalable enantioselective nickel-catalyzed electrochemical reductive homocoupling of aryl bromides has been developed, affording enantioenriched axially chiral biaryls in good yield under mild co

NIAID Data Ecosystem30

Bis(imidazolidine)pyridine-NiCl 2 Catalyst for Nitro-Mannich Reaction of Isatin-Derived N ‑Boc Ketimines: Asymmetric Synthesis of Chiral 3‑Substituted 3‑Amino-2-oxindoles

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吲哚衍生物制备

An (S,S)-diphenyldiamine-derived bis(imidazolidine)pyridine (PyBidine)-NiCl2 complex catalyzed the nitro-Mannich reaction of isatin-derived N-Boc ketimines to construct a chiral quaternary aminocarb

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Catalytic Asymmetric Access to Noncanonical Chiral α‑Amino Acids from Cyclic Iminoglyoxylates and Enamides

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手性氨基酸衍生物

Here we describe an enantioselective Mannich reaction of cyclic iminoglyoxylates with enamides by virtue of chiral phosphoric acid catalysis in a one-pot manner. The wide substrate scope, mild reactio

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Catalytic Enantioselective Additions of Indoles to Nitroalkenes

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