Highly Diastereoselective Addition of Cinnamylzinc Derivatives to α-Chiral Carbonyl Compounds
收藏NIAID Data Ecosystem2026-03-06 收录
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Cinnamylzinc reagents react with cyclic and acyclic α-chiral ketones under very mild conditions (−78 °C, 1 h), yielding the corresponding homoallylic alcohols bearing three adjacent stereocenters with high diastereoselectivity. An extension of this reaction to enantioenriched α-chiral ketones is also described.
创建时间：
2016-06-03
