Anion−π−π Interactions in a Dinuclear M₂L₂ Metallocycle

The combination of the square-planar cis-protected [Pt(dppp)(O3SCF3)2] (M) with the ditopic N,N′-bis(3,5-dimethyl-4-pyridinyl)-4-ethoxy-2,6-pyridinedicarboxamide ligand (L) leads both in solution and in the solid state to the quantitative self-assembly of a M2L2 metallocycle. We also report crystallographic evidence derived from the solid-state structure of the dinuclear metallocycle in support of the existence of anion−π−π interactions.