Metal Scrambling in the Trinuclear {Pt<sub>2</sub>Se<sub>2</sub>M} (M = Pt, Pd, Au) System Using an Electrospray Mass Spectrometry (ESMS) Directed Synthetic Methodology; Isolation and Crystallographic Characterization of {Pt<sub>2</sub>(μ<sub>3</sub>-Se)<sub>2</sub>(PPh<sub>3</sub>)<sub>4</sub>[Pt(cod)]}{PF<sub>6</sub>}<sub>2</sub> and {Pt(μ<sub>3</sub>-Se)<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>[Pt(cod)]<sub>2</sub>}{PF<sub>6</sub>}<sub>2</sub> (cod = Cyclo-octa-1,5-diene)
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数据链接：
https://figshare.com/articles/dataset/Metal_Scrambling_in_the_Trinuclear_Pt_sub_2_sub_Se_sub_2_sub_M_M_Pt_Pd_Au_System_Using_an_Electrospray_Mass_Spectrometry_ESMS_Directed_Synthetic_Methodology_Isolation_and_Crystallographic_Characterization_of_Pt_sub_2_sub_sub_3_sub_-Se_sub_2_sub_PPh_sub_3_/3604278数据链接链接失效反馈
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资源简介：
Pt2(μ-Se)2(PPh3)4 reacts with PtCl2(cod) to give {Pt2(μ3-Se)2(PPh3)4[Pt(cod)]}2+ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ3-Se)2(PPh3)2[Pt(cod)]2}2+. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected.
创建时间：
2016-08-17
