“Oxide Route” for the Preparation of Mercury(II) N-Heterocyclic Carbene Complexes
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Imidazolium salts react with HgO to give mono-NHC dihalomercury(II) complexes in acceptable yields. The solid-state structures of several examples were determined by X-ray diffraction. The complexes consist of monomeric (NHC)HgX2 units, which feature tricoordinated mercury atoms, a structural arrangement rarely found for mercury compounds.
创建时间:
2016-02-23



