Metal-Free Transfer Hydrogenation Catalysis by B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>
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The activation of amines by B(C6F5)3 is shown to effect the catalytic racemization of a chiral amine. Extending this strategy to a bimolecular process, catalytic transfer hydrogenation of imines, enamines, and N-heterocycles is demonstrated using iPr2NH as the source of hydrogen and a catalytic amount of the Lewis acid B(C6F5)3.
创建时间:
2011-09-12



