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Nanoscale Aryleneethynylene Molecular Wires with Reversible Fluorenone Electrochemistry for Self-Assembly onto Metal Surfaces

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Two rigid-rod conjugated molecules (11 and 12) of ca. 4 and 7 nm length, respectively, bearing protected terminal thiol groups have been synthesized via multistep Sonogashira coupling reactions and shown to possess reversible cathodic solution electrochemistry arising from reduction of the fluorenone units.

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2016-05-07
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