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Optically Active Dinuclear Palladium Complexes Containing a Pd−Pd Bond: Preparation and Enantioinduction Ability in Asymmetric Ring-Opening Reactions

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NIAID Data Ecosystem2026-03-06 收录
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Optically active dinuclear palladium complexes containing a Pd−Pd bond were prepared by using (R,R)-bis(tert-butylmethylphosphino)methane ((R,R)-t-Bu-MiniPHOS). The dinuclear palladium complexes coupled with silver triflate exhibited good to excellent enantioselectivities up to 99% in palladium-catalyzed alkylative ring-opening reactions of azabenzonorbornadienes.

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2016-02-26
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