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Triple Helicate Constructed by Covalent Bondings: Crystal Structure and Effective Synthesis Based on Propeller-like Substructures

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NIAID Data Ecosystem2026-03-06 收录
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A triple helicate, having a macrocyclic aromatic amide structure, was synthesized in high yield because of a preorganized component of the tertiary benzenetrianilide moieties in a propeller-like syn conformation at both ends. The helicity was derived from tilted T-shaped aromatic−aromatic (CH−π) interactions between each of the N-phenyl rings.

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2016-05-05
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