Osmium-Promoted Dehydrogenation of Amine–Boranes and B–H Bond Activation of the Resulting Amino–Boranes
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The five-coordinate osmium complex OsH(SH)(CO)(PiPr3)2, containing an electrophilic center bonded to the soft hydrogen sulfide ligand, promotes dehydrogenation of amine–boranes and captures the amino–borane products, forming hydrogenaminothioborate complexes.
创建时间:
2016-02-18



