Covalent Modification of Diruthenium Alkynyl Compounds: Novel Application of <i>Click</i> Reactions in Organometallic Chemistry
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Diruthenium alkynyl compounds containing one or two 1,2,3-triazoles were prepared via the Cu(I)-catalyzed 1,3-dipolar cycloaddition reaction (click reaction). Electrochemical, magnetic, and molecular structural features of the click products indicate that peripheral modification with the 1,2,3-triazole substituent induces minimal changes in both the molecular structure and electronic properties of Ru2 alkynyl compounds.
创建时间:
2016-05-06



