Synthesis of New Chiral N-Heterocyclic Carbene−Imine Ligands and Their Application to an Asymmetric Allylic Alkylation Reaction
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Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)−imine ligands derived from trans-1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.
创建时间：
2016-05-07
