Chiral Polycyclic Ketones via Desymmetrization of Dihaloolefins
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
3-Chloronorbornenone (R)-1a (98% ee) was obtained from trichloronorbornene 5 in two steps by the in situ generation of dichloronorbornadiene 2a with t-BuOK and desymmetrization with (−)-ephedrine, followed by hydrolysis with PPTS. The generality of this desymmetrization with (−)-ephedrine was tested with dibromonorbornadiene 2c and other substituted dichloronorbornadienes.
创建时间：
2016-02-29
