Enantioselective Nickel-Catalyzed Hydrocyanative Desymmetrization of Norbornene Derivatives
收藏NIAID Data Ecosystem2026-03-12 收录
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A nickel-catalyzed enantioselective hydrocyanation of N-aryl 5-norbornene-endocis-2,3-dicarboximides was reported. This desymmetrization process allows for a quick construction of both continuous stereogenic carbon centers and remote N–CAr atropisomeric chirality. Mechanism studies indicated that the resident carbonyl group of the substrates plays a key role in the enantioselectivity.
创建时间：
2021-06-09
