Slip−Inversion−Slip Mechanism of Phosphametallocene Isomerization. Spectroscopic Characterization of an (η<sup>1</sup>-Phospholyl)titanium Complex. Synthesis and Structures of Chiral Mono(phospholyl)titanium Complexes
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The first reported synthesis and spectroscopic characterization of a group 4 η1-phospholyl complex, (η1-dibenzophospholyl)tris(dimethylamido)titanium, are documented, which has an η1-phospholyl ligand analogous to those proposed in the slip−inversion−slip mechanism of phosphametallocene isomerization.
创建时间:
2006-02-27



