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Highly Enantioselective Quinoline Synthesis via Ene-type Cyclization of 1,7-Enynes Catalyzed by a Cationic BINAP−Palladium(II) Complex

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NIAID Data Ecosystem2026-03-06 收录
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The first highly enantioselective synthesis of a six-membered ring quinoline catalyzed by a cationic BINAP−palladium(II) complex is shown to afford the quinoline products having a quaternary carbon center or a spiro-ring in quantitative yield and >99% ee.

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2016-08-18
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