Rhodium-Catalyzed Asymmetric Arylation of <i>N</i>-Tosyl Ketimines
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A rhodium-catalyzed addition of sodium tetraarylborates to N-tosyl ketimines is described. Highly efficient asymmetric catalysis has been achieved by employing a chiral diene ligand, constructing chiral amine derivatives possessing α-tetrasubstituted carbon stereocenters with high enantioselectivity.
创建时间：
2010-09-29
