Evidence for a Ni<sup>I</sup> Active Species in the Catalytic Cross-Coupling of Alkyl Electrophiles
收藏NIAID Data Ecosystem2026-03-06 收录
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Addition of terpyridine to (TMEDA)Ni(CH3)2 results in the high-yield formation of (terpyridyl)NiMe (3). This NiI organometallic complex was found to be capable of transferring its methyl group to iodocyclohexane to produce methylcyclohexane in high yield. Compound 3 can also serve as an initiator for the catalytic cross-coupling of alkyl electrophiles performed under Negishi-like conditions.
创建时间：
2004-07-07
