Tandem Chain Extension−Aldol Reaction: Syn Selectivity with a Zinc Enolate
收藏NIAID Data Ecosystem2026-03-06 收录
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A tandem chain extension−aldol reaction was developed in which β-keto esters are transformed to α-substituted-γ-keto esters in an efficient zinc-mediated, one-pot reaction. The diastereoselectivity of the reaction ranged from good to excellent with syn stereochemistry observed for β-keto ester and amide substrates and anti-stereochemistry observed for a β-keto imide.
创建时间：
2016-08-20
