Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2‑Alkenylphenols and Alkynes
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资源简介：
Appropriately substituted 2-alkenylphenols undergo a mild formal [3C+2C] cycloaddition with alkynes when treated with a Rh(III) catalyst and an oxidant. The reaction, which involves the cleavage of the terminal C–H bond of the alkenyl moiety and the dearomatization of the phenol ring, provides a versatile and efficient approach to highly appealing spirocyclic skeletons and occurs with high selectivity.
创建时间：
2015-12-17
