Remarkable Stereoselectivity in Intramolecular Borono-Mannich Reactions: Synthesis of Conduramines
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An unprecedented intramolecular Petasis condensation provides a novel approach to biologically important conduramines. The compounds are produced with an exclusive anti stereoselectivity for the newly created β-amino alcohol motif. The stereochemical outcome of the reaction is opposite to the one usually observed in the intermolecular reaction.
创建时间：
2016-02-22
