<i>cis</i>-2,5-Diaminobicyclo[2.2.2]octane, a New Scaffold for Asymmetric Catalysis via Salen−Metal Complexes
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A new C2 symmetric salen scaffold based on cis-2,5-diaminobicyclo[2.2.2]octane has been synthesized that forms complexes with a wide range of metals. The chromium(III) complex is shown to catalyze the hetero-Diels−Alder reaction and the Nozaki−Hiyama−Kishi reaction with high efficiency and excellent stereoselectivity.
创建时间:
2011-05-06



