In this article the utility of phosphoramidite ligands in enantioselective AuI catalysis was explored in the development of highly diastereo- and enantioselective AuI-catalyzed cycloadditions of allen

NIAID Data Ecosystem20

Au(I)-Catalyzed Enantioselective 1,3-Dipolar Cycloadditions of Münchnones with Electron-Deficient Alkenes

金催化不对称环加成

Δ-吡咯啉立体选择性合成

The first catalytic enantioselective 1,3-dipolar cycloaddition of münchnone dipoles with electron-deficent alkenes is described. The reaction is catalyzed by chiral bis(phosphine)gold(I) benzoate comp

NIAID Data Ecosystem20

Au-Catalyzed Asymmetric Formal [3 + 2] Cycloaddition of Isocyanoacetates with Maleimides

金催化不对称环加成

手性杂环合成

An efficient protocol for the AuI-catalyzed asymmetric formal [3 + 2] cycloaddition of isocyanoacetates with phenylmaleimide has been developed. In the presence of cationic AuI/DTBM-segphos complex, e

NIAID Data Ecosystem40

Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition of Allene-dienes

金催化不对称环加成

手性合成

An enantioselective gold(I)-catalyzed intramolecular [4 + 2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine

NIAID Data Ecosystem20

Data for: Dataset of asymmetric intramolecular [4+3] cycloaddition reactions catalyzed by NHC-gold(I) complexes

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