The metal-linker coordination bond in metal–organic frameworks (MOFs) can be unstable in humid and acid gas environments, leading to loss of crystallinity and porosity. This degradation is not necessa
Crystal-to-crystal transformation from a 3D interpenetrated-type MOF {[Cu(BF4)2(bpy)(H2O)2] (bpy)} (1) to a 2D square-grid-type [Cu(BF4)2(bpy)2] (2) (bpy = 4,4‘-bipyridine) was observed. It was derive
The structure transformation of a metal–organic framework (MOF) constructed by a pyrene-based ligand 1,3,6,8-tetrakis(3,5-isophthalic acid)pyrene (H8TIAPy), [Zn4(TIAPy)·(DMSO)2·(H2O)4]·(Guest) (J
The self-assembly of silver(I) salts with bitopic triazole ligands 4-(salicylideneamino)-1,2,4-triazole (L1) and 4-(2-pyridinyl)-1,2,4-triazole (L2) produced dinuclear complexes and a 1D molecular-lad
we demonstrate that a 2D semiconducting antiferromagnetic Cu-MOF can be endowed with intrinsic room-temperature ferromagnetic coupling using a ligand cleavage strategy to regulate the inner magnetic i