An Undecanuclear Ferrimagnetic Cu9Dy2 Single Molecule Magnet Achieved through Ligand Fine-Tuning
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We describe the concept of increasing the nuclearity of a previously reported high-spin Cu5Gd2 core using a “fine-tuning” ligand approach. Thus, two Cu9Ln2 coordination clusters, with Ln = Dy (1) and Gd (2), were synthesized with the Gd compound having a ground spin state of 17/2 and the Dy analogue showing single-molecule-magnet behavior in zero field.
创建时间：
2016-04-26
