Enantioselective Palladium-Catalyzed Carbozincation of Cyclopropenes
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A highly enantioselective palladium-catalyzed carbozincation of cyclopropenes has been developed. The intermediate cyclopropylzinc species, after transmetalation with copper, were trapped with various electrophiles. This one-pot procedure furnished functionalizied cyclopropenes with excellent diastereo- and enantioselectivity.
创建时间:
2016-02-23



