(η<sup>5</sup>-Halogenocyclohexadienyl)Mn(CO)<sub>3</sub> Complexes: Halogen Substitution by Arene Derivatives
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Unprecedented coupling reactions on (η5-chlorocyclohexadienyl)tricarbonyl manganese complexes with arenes create a new carbon−carbon bond on the conjugated system, keeping intact the η5-chlorocyclohexadienyl moiety; thus, the removal of the exo hydrogen bond of the sp3 CH2 group yields efficiently new cationic (η6-arene) manganese complexes which cannot be prepared directly from the free arene.
创建时间：
2016-08-26
