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A Potential Intermediate for the Aza-Corey−Chaykovsky Reaction: Synthesis, Structure, and Thermolysis of a Pentacoordinate 1,2-Thiazetidine 1-Oxide

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Thermolysis of a pentacoordinate 1λ6,2-thiazetidine, which was synthesized for the first time and characterized by X-ray crystallographic analysis, gave the corresponding aziridine and a cyclic sulfinate almost quantitatively. The potential intermediacy of a 1λ6,2-thiazetidine was suggested in the aza-Corey−Chaykovsky reaction.

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2006-09-28
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