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Enantioselective Total Synthesis of (+)-Salvileucalin B

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NIAID Data Ecosystem2026-03-06 收录
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An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is reported. Key findings include a copper-catalyzed arene cyclopropanation reaction to provide the unusual norcaradiene core and a reversible retro-Claisen rearrangement of a highly functionalized norcaradiene intermediate.

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2016-02-23
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