Data for: Tuning the Latent Behavior of Molybdenum Imido Alkylidene N-Heteroc...

B2FIND2026-03-19 收录

有机金属催化

配合物合成

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https://b2find.eudat.eu/dataset/c7d15495-3520-5a56-ac5b-8ad3e11aef51 数据链接链接失效反馈

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We report the synthesis of O- and N-chelated hexacoordinated molybdenum imido alkylidene N-heterocyclic carbene (NHC) bistriflate and pentacoordinated molybdenum imido...

Solvent Effects and Activation Parameters in the Competitive Cleavage of C−CN and C−H Bonds in 2-Methyl-3-Butenenitrile Using [(dippe)NiH] 2

有机金属催化

反应机理

The reaction of [(dippe)NiH]2 with 2-methyl-3-butenenitrile (2M3BN) in solvents spanning a wide range of polarities shows significant differences in the ratio of C−H and C−CN activated products. C−H c

NIAID Data Ecosystem150

Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation

有机金属催化

C-F键活化

The Ru–S bond in Ohki–Tatsumi complexes breaks oligomeric DIBAL-H structures into their more reactive monomer. That deaggregation is coupled to heterolytic Al–H bond activation at the Ru–S bond, forma

Figshare2017-11-03 更新20

Copper(I) Complexes derived from Mono- and Diphosphino-Boranes: Cu→B Interactions Supported by Arene Coordination

金属有机化学

配合物合成

The monophosphino-boranes o-iPr2P(C6H4)BR2 (1: R = Ph and 3: R = Cy) and diphosphino-boranes [o-R2P(C6H4)]2BPh (5: R = Ph and 6: R = iPr) readily react with CuCl to afford the corresponding complexes

NIAID Data Ecosystem20

Hexanuclear Copper(I) Hydride from the Reduction-Induced Decarboxylation of a Dicopper(II) Formate

配合物合成

甲酸脱氢催化

Copper(I) hydride complexes represent a promising entry into formic acid dehydrogenation catalysis. Herein we present the spontaneous decarboxylation of a μ1,3-formate-bridged dicopper(II) complex (

NIAID Data Ecosystem100

Regioselectivity of Stoichiometric Metathesis of Vinylsilanes with Second-Generation Grubbs Catalyst: A Combined DFT and Experimental Study

有机金属催化

复分解反应

The regioselectivity of metathesis reactions of trisubstituted vinylsilanes H2CCHSiR3 (SiR3 = SiCl3, SiCl2Me, SiClMe2, SiMe3, Si(OEt)3) with the second-generation ruthenium alkylidene complex has be

Figshare2016-08-04 更新20

Data for: Tuning the Latent Behavior of Molybdenum Imido Alkylidene N-Heteroc...

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