Kinetic analysis of catalytic reactions is a powerful tool for mechanistic elucidation but is often challenging to perform. Establishing order in a catalyst is achieved by running several reactions at
Inputs, outputs and orbitals for the species present in the uncatalyzed addition of azides to iodoalkynes, discussed in: Pedro J. Silva and Carlos E. P. Bernardo (2018), Influence of
Background: So far, 3 randomized controlled trials have shown that the endobronchial treatment using coils is safe and effective. However, the more exact underlying mechanism of the trea
[Mg2(μ-Cl)3(THF)6][2,5-(CtBu)2-1,3,4-P3] and K[2,5-(CtBu)2-1,3,4-P3] are formed quantitatively from reduction of the tricyclic-triphosphorus compound ClP3(CtBu)2 with Mg or K; the mechanistic insights
