Diaceno[<i>a</i>,<i>e</i>]pentalenes from Homoannulations of <i>o</i>‑Alkynylaryliodides Utilizing a Unique Pd(OAc)<sub>2</sub>/<i>n</i>‑Bu<sub>4</sub>NOAc Catalytic Combination
收藏NIAID Data Ecosystem2026-03-09 收录
数据链接：
官方服务：
资源简介：
A heterogeneous catalytic system, Pd(OAc)2/n-Bu4NOAc, for the efficient synthesis of diaceno[a,e]pentalenes via a tandem Pd catalytic cycle is reported. The catalytic partner n-Bu4NOAc played indispensable and versatile roles, acting as both the media for recovering active Pd(0) species and their stabilizer. A series of new diaceno[a,e]pentalenes were obtained in moderate to high yields, among which the octacyclic dianthracenopentalene was found to be highly emissive.
创建时间：
2016-02-16
