A General Modular Method of Azaindole and Thienopyrrole Synthesis <i>via</i> Pd-Catalyzed Tandem Couplings of <i>gem</i>-Dichloroolefins
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A palladium-catalyzed reaction of gem-dichloroolefins and a boronic acid via a tandem intramolecular C−N and intermolecular Suzuki coupling process gave corresponding substituted azaindoles or thienopyrroles. This method is a very modular protocol to synthesize all four isomers of azaindole and two isomers of thienopyrroles in good to excellent yield.
创建时间：
2016-02-29
