Palladium/l‑Proline-Catalyzed Enantioselective α‑Arylative Desymmetrization of Cyclohexanones
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A highly enantioselective palladium/l-proline-catalyzed α-arylative desymmetrization of cyclohexanones was developed. The new strategy for α-arylation reaction led to a series of optically active morphan derivatives bearing α-carbonyl tertiary stereocenters in good yields with excellent enantioselectivities (up to 99% ee).
创建时间：
2016-04-21
