[(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Supporting Ligands for Reactions at Group VI Metal−Copper Bonds
收藏NIAID Data Ecosystem2026-03-06 收录
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Salts of [(2-(diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates react with CuCl to afford useful intermediates that permit installation of phosphines at copper(I), in a rare instance of nucleophilic attack at heterobimetallic M−Cu bonds without concomitant heterolytic cleavage.
创建时间:
2016-02-27



