Dataset for Concave P-Stereogenic Phosphorodiamidite Ligands for Enantioselective Rh(I)-Catalysis

The development of a new class of concave P-stereogenic phosphorodiamidite ligands, derived from Tröger Bases (TBs), is explored. These ligands, characterized by their remarkable stability and unique structural geometry around the P-atom, are used in asymmetric Rh(I)-catalyzed additions of boronic acids to NH-isatins resulting in excellent reactivities and reasonable enantioselectivity (e.r. up to 92:8).