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Synthesis of Amides and Nitriles from Vinyl Azides and <i>p</i>‑Quinone Methides

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NIAID Data Ecosystem2026-03-10 收录
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A divergent synthesis of amides and nitriles from vinyl azides and p-quinone methides (p-QMs) was developed. The p-QMs could be activated by BF3-Et2O and then nucleophilically attacked by vinyl azides, leading to divergent rearrangement toward amides and nitriles.

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2017-03-24
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