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Synthesis and Characterization of the Ferrio-Substituted Silicon(II) Compound Me<sub>5</sub>C<sub>5</sub>(CO)<sub>2</sub>FeSiC<sub>5</sub>Me<sub>5</sub>

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Reaction of the (pentamethylcyclopentadienyl)silicon cation with the (pentamethylcyclopentadienyl)dicarbonylferrate anion leads to the formation of the crystalline, thermolabile silicon(II) compound [(η5-pentamethylcyclopentadienyl)dicarbonylferrio](η3-pentamethylcyclopentadienyl)silicon. The singlet−triplet energy difference ΔEST is calculated to be 25.4 kcal/mol.

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2010-11-08
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