Phosphorescence decay curves, excitation-emission matrices (EEMs), and input and output parameters of parallel factor analysis for the determination of benzonaphthothiophenes

Excitation-emission matrices (EEMs) for binary mixtures of benzo[b]naptho[1,2-b]thiophene (BbN12T) and benzo[b]naptho[2,1-b]thiophene (BbN21T) and synthetic mixtures of BbN12T and BbN21T with interference were collected at 77K with the aid of a Fluoromax (Horiba Jobin Yvon) using a pulsed lamp, fiber optic probe (FOP), and shpol'skii solvents. These data were subjected to parallel factor analysis (PARAFAC). Phosphorescence decay curves for benzonaphthothiophenes were collected with the aid of a Fluoromax (Horiba Jobin Yvon) using a pulsed lamp, FOP, and shpol'skii solvents. Triplicate spectra of supplemental material at RT, 77K, and 4.2K were also recorded with the aid of a Fluoromax (Horiba Jobin Yvon) using continuous wave lamp, FOP, and shpol'skii solvents. This dataset supports the publication: Al-Tameemi, M., Arif, S., Campiglia, A. D., Wilson, W. B., & Wise, S. A. (2018). Photoluminescence Spectroscopy of Anthrathiophenes and Benzonaphthothiophenes in Shpol’skii Matrixes. Talanta. doi:10.1016/j.talanta.2018.10.044本数据集采集了苯并[b]萘并[1,2-b]噻吩（benzo[b]naptho[1,2-b]thiophene，简称BbN12T）与苯并[b]萘并[2,1-b]噻吩（benzo[b]naptho[2,1-b]thiophene，简称BbN21T）的二元混合物，以及含干扰组分的BbN12T与BbN21T人工混合体系的激发发射矩阵（Excitation-emission matrices，简称EEMs），采集温度为77K，实验借助Horiba Jobin Yvon品牌的Fluoromax光谱仪完成，采用脉冲灯、光纤探头（FOP）及什波尔斯基溶剂（Shpol'skii solvents）。上述数据已通过平行因子分析（PARAFAC）进行处理。 本数据集同时采集了苯并萘并噻吩类化合物的磷光衰减曲线，采集设备与实验条件同上，即采用Horiba Jobin Yvon品牌的Fluoromax光谱仪、脉冲灯、FOP及什波尔斯基溶剂。 此外，还在室温（RT）、77K及4.2K条件下，借助Horiba Jobin Yvon品牌的Fluoromax光谱仪，采用连续波灯、FOP及什波尔斯基溶剂，对补充材料进行了三次重复光谱采集。 本数据集支撑以下已发表学术论文：Al-Tameemi, M., Arif, S., Campiglia, A. D., Wilson, W. B., & Wise, S. A. (2018). 什波尔斯基基质中蒽并噻吩与苯并萘并噻吩类的光致发光光谱. Talanta. doi:10.1016/j.talanta.2018.10.044