Iodine(III)-Mediated Selective Intermolecular C–H Amination for the Chemical Diversification of Tryptamines
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Defined hypervalent iodine reagents of the general structure PhI[N(SO2R)(SO2R′)]2 promote the selective direct C–H-amination of the indole core of various tryptamines. Starting from a general C2-amination strategy, subsequent transformations enable a variety of site-selective functionalizations, which proceed with noteworthy high chemoselectivity and provide an overall access to structurally diversified products.
创建时间：
2016-08-01
