Triple Boron-Cored Chromophores Bearing Discotic 5,11,17-Triazatrinaphthylene-Based Ligands
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A series of novel chromophores fused with multiple boron cores have been successfully synthesized by the complexation of three difluoroboryl or diphenylboryl at the periphery of 5,11,17-triazatrinaphthylene derivative ligands. Their sterically congested molecular scaffolds with expanded π-conjugated discotic backbones render them with unique electronic properties including large Stokes shifts, tunable electrochemical behaviors, and low-lying LUMO energy levels up to −3.18 eV.
创建时间：
2016-03-14
