Enantioselective Synthesis of Trifluoromethyl-Substituted Cyclopropanes
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资源简介：
The reaction of 1-aryl-2,2,2-trifluorodiazoethanes with alkenes, catalyzed by the adamantylglycine-derived dirhodium complex Rh2(R-PTAD)4, generates trifluoromethyl-substituted cyclopropanes with high diastereoselectivity (>94%) and enantioselectivity (88−>98%).
创建时间：
2016-02-29
