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Positional Control of Encapsulated Atoms Inside a Fullerene Cage by Exohedral Addition

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NIAID Data Ecosystem2026-03-06 收录
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The exohedrally functionalized derivative of endohedral metallofullerene, Ce2@C80(Mes2SiCH2SiMes2), was successfully synthesized and fully characterized. X-ray crystallographic and NMR spectroscopic analyses reveal that the free random motion of two metal atoms in Ce2@C80 is controlled inside the cage by exohedral chemical functionalization.

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2016-05-05
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